Of the series of pictures I took for my night photography class, this one is probably pushing it in regards to when I took it. It was taken at 6:26am, so the sun was thinking about coming up, but you could still some of the night sky:
As you can see from the camera data, it is a really long exposure, 189 seconds. That is Venus you can see in the sky. I really like the way the color turned out in this photo.
Cheers!